Utilizing a diamond-like carbon (DLC) coating on rubber surfaces is an innovative approach to improve the wear resistance and tribological characteristics of rubber. In this paper, a series of N-doped diamond-like thin films (N-DLC) were deposited on the surface of nitrile butadiene rubber (NBR) substrate by varying the flow rate of nitrogen using direct current magnetron sputtering (DC-MS) technology, and the effects of nitrogen flow rate on the surface morphology, structure, surface energy and tribological properties of N-DLC films were systematically investigated. The results show that the friction coefficients of the N-DLC films are all smaller than those of the undoped DLC films, and most importantly, the samples maintain a stable, ultra-low coefficient of friction of about 0.057 and a low wear rate of the order of 10−9 in the tribological tests at a nitrogen flow rate of 3 sccm, exhibiting excellent tribological performance. This is attributed to several key factors: higher hardness, better film-base bonding, lower surface roughness, and lower friction interface adhesion. This recognition provides insight into the preparation of N-DLC films on rubber to achieve low frictional wear.