3D printing has shown promise in the development of notable sensing and health detection devices. Nonetheless, challenges remain in the concurrent development of highly durable wearable sensors with low-friction surfaces. This challenge serves as a limiting factor in the operational lifespans of these sensors. In this study, a magnetically assisted 3D printing technique is developed to fabricate composites reinforced with magnetic Fe3O4@SiO2 nanochains (NCs) with dimensions of 60.2 µm in length (L) and 0.2 µm in diameter (D), indicating an L:D ratio exceeding 300. By applying a vertical magnetic field and extrusion flow field to the sensor's surface layer, the NCs can be arranged differently (together with the printed textures), reducing the coefficient of friction by 27.7% and improving the wear resistance. This approach is inspired by nacre, known for its impressive durability and resilience. A motion monitoring sensor with an extended lifespan is successfully fabricated by using liquid metal ink integrated with an anti-wear layer. These findings offer significant insights into the evolution of wearable sensors, demonstrating their adaptability to multi-material printing and resulting in improved performance and service lives.