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Production of polyol ester lubricants for refrigeration systems

专利摘要

A poly(neopentylpolyol) ester composition is produced by reacting a neopentylpolyol having the formula:wherein each R is independently selected from the group consisting of CH3, C2H5 and CH2OH and n is a number from 1 to 4, with at least one monocarboxylic acid having 2 to 15 carbon atoms in the presence of an acid catalyst and at an initial mole ratio of carboxyl groups to hydroxyl groups of greater than 0.5:1 to 0.95:1 to form a partially esterified poly(neopentylpolyol) composition. Then the partially esterified poly(neopentylpolyol) composition is reacted with additional monocarboxylic acid having 2 to 15 carbon atoms to form a final poly(neopentylpolyol) ester composition. ......

基本信息

专利类型:
发明专利
申请/专利号:
US12/691300
申请日期:
2010-01-21
专利申请人:
科聚亚公司
分类号:
C10M105/38
发明/设计人:
CARR, DALE ， HUTTER, JEFFREY ， KELLEY, RICHARD ， HESSELL, EDWARD T. ， URREGO, ROBERTO
权利要求: 1. A poly(neopentylpolyol) ester composition produced by:(i) reacting pentaerythritol with a mixture of monocarboxylic acids selected from n-pentanoic acid, iso-pentanoic acid, n-hexanoic acid, n-heptanoic acid, n-octanoic acid, n-nonanoic acid and iso-nonanoic acid,wherein said mixture comprises from about 2 to about 6 moles of n-pentanoic acid and from about 0 to about 3.5 moles of n-heptanoic acid per mole of iso-nonanoic acid, in the presence of an acid catalyst and at an initial mole ratio of carboxyl groups to hydroxyl groups of greater than 0.5:1 to 0.95:1 to form a partially esterified poly(neopentylpolyol) composition;and(ii) reacting the partially esterified poly(neopentylpolyol) composition produced in (i) with additional monocarboxylic acid, wherein the additional monocarboxylic acid employed comprises the same carboxylic acids employed in (i)andwherein the polyol ester composition comprises monopentaerythritol esters, dipentaerythritol esters and polypentaerythritol esters in a weight ratio of mono- to di- to polypentaerythritol esters of about 76:16:8 to about 60:20:20 and has a viscosity index in excess of 95.2. The ester composition of claim 1, wherein the initial mole ratio of carboxyl groups to hydroxyl groups is from 0.7:1 to 0.85:1.3. The ester composition of claim 1, wherein said mixture of monocarboxylic acids comprises from about 1.75 to about 2.25 moles of n-pentanoic acid and 0.75 to about 1.25 moles of n-heptanoic acid per mole of iso-nonanoic acid.4. The ester composition of claim 2, wherein said mixture of monocarboxylic acids comprises from about 1.75 to about 2.25 moles of n-pentanoic acid and 0.75 to about 1.25 moles of n-heptanoic acid per mole of iso-nonanoic acid.5. A poly(neopentylpolyol) ester composition produced by:(i) reacting pentaerythritol with a mixture of monocarboxylic acids selected from n-pentanoic acid, iso-pentanoic acid, n-hexanoic acid, n-heptanoic acid, n-octanoic acid, n-nonanoic acid and iso-nonanoic acid,wherein said mixture comprises from about 1 to about 10 moles of iso-nonanoic acid and 0 to about 1 moles of n-heptanoic acid per mole of iso-pentanoic acid,in the presence of an acid catalyst and at an initial mole ratio of carboxyl groups to hydroxyl groups of greater than 0.5:1 to 0.95:1 to form a partially esterified poly(neopentylpolyol) composition;and(ii) reacting the partially esterified poly(neopentylpolyol) composition produced in (i) with additional monocarboxylic acid, wherein the additional monocarboxylic acid employed comprises the same carboxylic acids employed in (i)andwherein the polyol ester composition comprises monopentaerythritol esters, dipentaerythritol esters and polypentaerythritol esters in a weight ratio of mono- to di- to polypentaerythritol esters of about 76:16:8 to about 60:20:20 and has a viscosity index in excess of 95.6. The ester composition of claim 5, wherein the initial mole ratio of carboxyl groups to hydroxyl groups is from 0.7:1 to 0.85:1.7. A working fluid comprising (a) a refrigerant and (b) a poly(neopentylpolyol) ester composition produced by:(i) reacting pentaerythritol with a mixture of monocarboxylic acids selected from n-pentanoic acid, iso-pentanoic acid, n-hexanoic acid, n-heptanoic acid, n-octanoic acid, n-nonanoic acid and iso-nonanoic acid,wherein said mixture comprises from about 2 to about 6 moles of n-pentanoic acid and from about 0 to about 3.5 moles of n-heptanoic acid per mole of iso-nonanoic acid,in the presence of an acid catalyst and at an initial mole ratio of carboxyl groups to hydroxyl groups of greater than 0.5:1 to 0.95:1 to form a partially esterified poly(neopentylpolyol) composition;and(ii) reacting the partially esterified poly(neopentylpolyol) composition produced in (i) with additional monocarboxylic acid, wherein the additional monocarboxylic acid employed comprises the same carboxylic acids employed in (i)andwherein the polyol ester composition comprises monopentaerythritol esters, dipentaerythritol esters and polypentaerythritol esters in a weight ratio of mono- to di- to polypentaerythritol esters of about 76:16:8 to about 60:20:20 and has a viscosity index in excess of 95.8. The working fluid of claim 7, wherein the initial mole ratio of carboxyl groups to hydroxyl groups is from 0.7:1 to 0.85:1.9. The working fluid of claim 7, wherein said mixture of monocarboxylic acids comprises from about 1.75 to about 2.25 moles of n-pentanoic acid and 0.75 to about 1.25 moles of n-heptanoic acid per mole of iso-nonanoic acid.10. The working fluid of claim 8, wherein said mixture of monocarboxylic acids comprises from about 1.75 to about 2.25 moles of n-pentanoic acid and 0.75 to about 1.25 moles of n-heptanoic acid per mole of iso-nonanoic acid.11. The working fluid of claim 7, wherein the refrigerant is a hydrofluorocarbon, a fluorocarbon or a mixture thereof.12. The working fluid of claim 11, wherein the refrigerant comprises a hydrofluorocarbon or fluorocarbon compound selected from difluoroethane (R-32) 1,1,1,2-tetrafluoroethane (R-134a), 1,1,2,2-tetrafluoroethane (R-134), pentafluoroethane (R-125) and tetrafluoropropene (R-1234yf).13. The working fluid of claim 7, wherein the refrigerant is selected from 1,1,1,2-tetrafluoroethane (R-134a), tetrafluoropropene (R-1234yf) and a mixture of 50 wt % difluoromethane and 50 wt % pentafluoroethane (R-410A).14. A working fluid comprising (a) a refrigerant and (b) a poly(neopentylpolyol) ester composition produced by:(i) reacting pentaerythritol with a mixture of monocarboxylic acids selected from n-pentanoic acid, iso-pentanoic acid, n-hexanoic acid, n-heptanoic acid, n-octanoic acid, n-nonanoic acid and iso-nonanoic acid,wherein said mixture comprises from about 1 to about 10 moles of iso-nonanoic acid and 0 to about 1 moles of n-heptanoic acid per mole of iso-pentanoic acid,in the presence of an acid catalyst and at an initial mole ratio of carboxyl groups to hydroxyl groups of greater than 0.5:1 to 0.95:1 to form a partially esterified poly(neopentylpolyol) composition;and(ii) reacting the partially esterified poly(neopentylpolyol) composition produced in (i) with additional monocarboxylic acid, wherein the additional monocarboxylic acid employed comprises the same carboxylic acids employed in (i)andwherein the polyol ester composition comprises monopentaerythritol esters, dipentaerythritol esters and polypentaerythritol esters in a weight ratio of mono- to di- to polypentaerythritol esters of about 76:16:8 to about 60:20:20 and has a viscosity index in excess of 95.15. The working fluid of claim 14, wherein the initial mole ratio of carboxyl groups to hydroxyl groups is from 0.7:1 to 0.85:1.16. The working fluid of claim 14, wherein the refrigerant is a hydrofluorocarbon, a fluorocarbon or a mixture thereof.17. The working fluid of claim 16, wherein the refrigerant comprises a hydrofluorocarbon or fluorocarbon compound selected from difluoroethane (R-32) 1,1,1,2-tetrafluoroethane (R-134a), 1,1,2,2-tetrafluoroethane (R-134), pentafluoroethane (R-125) and tetrafluoropropene (R-1234yf).18. The working fluid of claim 14, wherein the refrigerant is selected from 1,1,1,2-tetrafluoroethane (R-134a), tetrafluoropropene (R-1234yf) and a mixture of 50 wt % difluoromethane and 50 wt % pentafluoroethane (R-410A).