This study used statistical tools to optimise WC/Co/Ni welds and model construction to improve the mechanical properties of coatings by laser cladding. The effect of the parameters on the wear performance of the weld was determined by analysis of variance. In addition, a polynomial model was constructed using the response surface method based on the experimental data of the orthogonal array designed by Taguchi. The experimental results show that there are white initial precipitation carbides and grey areas of WC mixed with Co and Ni compounds, while less wear and less plastic deformation are observed with WC/Co/Ni alloys. By adding Co/Ni alloys, the composite coating extension is seen to have good anti-wear performance. Based on the regression model, a pairwise interaction model was successfully constructed and further modelling of the 3D contour of the wear behaviour was explored. Comparing all the experiments, the predictions of the interaction model were found to be reliable, with an average error of 8.75%. The findings show that there is a very close match between the predicted values of RSM for wear performance and the experimental data, which proves the effectiveness of the Taguchi design-based RSM in improving the mechanical properties of laser cladding.